Electrosynthesis of gold nanocomposites based on a copolymer of 1-vinyl-1,2,4-triazol with crotonic acid

Original scientific paper

  • Serzhik H. Sargsyan National Polytechnic University of Armenia, Teryan 105, 0009 Yerevan, Armenia https://orcid.org/0000-0002-5102-3873
  • Artur S. Sargsyan Yerevan State Medical University after Mkhitar Heratsi, Koryun 2, 0025 Yerevan, Armenia https://orcid.org/0000-0002-5102-3873
  • Tatevik S. Sargsyan Yerevan State Medical University after Mkhitar Heratsi, Koryun 2, 0025 Yerevan, Armenia
  • Karina M. Khizantsyan Yerevan State Medical University after Mkhitar Heratsi, Koryun 2, 0025 Yerevan, Armenia https://orcid.org/0000-0002-5102-3873
  • Ida G. Agadjanyan National Polytechnic University of Armenia, Teryan 105, 0009 Yerevan, Armenia
  • Karina S. Margaryan Yerevan State Medical University after Mkhitar Heratsi, Koryun 2, 0025 Yerevan, Armenia
Keywords: Electrolysis, nanocomposite film, electropolymerization, medicine, thermal stability
Graphical Abstract

Abstract

In this work, we have synthesized and discussed the results of electrosynthesis of metal-polymer nanocomposites of gold. Nanocoatings were made on pure iron and steel electrodes by combining the process of electropolymerization of 1-vinyl-1.2.4-triazole with crotonic acid and cathodic deposition of gold. Using UV, IR and atomic absorption spectro­scopies, X-ray phase analysis, as well as thermogravimetric and elemental analyses, the structure and composition of the synthesized nanocomposites and nano­composite coatings were studied.

Downloads

Download data is not yet available.

References

A. D. Pomogailo, A. S. Rosenberg, I. E. Uflyand, Metal Nanoparticles in Polymers, Khimiya, Moscow, Russia, 2000.

C. N. R. Rao, A. Müller, A. K. Cheetham (Eds.), The Chemistry of Nanomaterials: Synthesis, Properties and Applications, Wiley-VCH Verlag GmbH & Co. Weinheim, Germany, 2004. ISBN 3-527-30686-2.

P. Broz (Ed.), Polymer-Based Nanostructures: Medical Applications, Roy. Soc. Chem. Pub., Cambridge, UK, 2010.

M. Noroozi, A. Zakaria, M. M. Moksin, Z. A. Wahab, A. Abedin, International Journal of Molecular Sciences 13(7) (2012) 8086-8096. https://doi.org/10.3390/ijms13078086

S. H. Sargsyan, K. S. Margaryan, Russian Journal of General Chemistry 84 (2014) 550-551. https://doi.org/10.1134/S1070363214030232

A. Tiwari (Ed.), Recent Developments in Bio-Nanocomposites for Biomedical Applications, Nova Science Publishers Inc., New York, USA, 2011, p. 511. ISBN 13: 9781617615139

L.-S. Wang, C.-Y. Wang, C.-H. Yang, C.-L. Hsieh, S.-Y. Chen, C.-Y. Shen, J.-J. Wang, K.-S. Huang International Journal of Nanomedicine 10(1) (2015) 2685-2696. https://doi.org/10.2147/IJN.S77410

G.F. Prozorova, A.S. Pozdnyakov, A.I. Emel'Yanov, S.A. Korzhova, T.G. Ermakova, B.A. Trofimov, Doklady Chemistry 449(1) (2013) 87-88. https://doi.org/10.1134/S00125008-13030051

R.A. Hule, D.J. Pochan. MRS Bulletin 32(4) (2007) 354-358. https://doi.org/10.1557/-mrs2007.235

F. Liebig, R. M. Sarhan, M. Bargheer, C. N. Z. Schmitt, A. H. Poghosyan, A. A. Shahinyan, J. Koetz, RSC Advances 10(14) (2020) 8152-8160. https://doi.org/10.1039/D0RA00729C

A. V. Meltonyan, A. H. Poghosyan, S. H. Sargsyan, K. S. Margaryan, A. A. Shahinyan Colloid and Polymer Science 297 (2019) 1345-1352. https://doi.org/10.1007/s00396-019-04554-x

A. V. Meltonyan, A. H. Poghosyan, S. H. Sargsyan, K. S. Margaryan, A. A. Shahinyan, Journal of Polymer Research 27 (2020) 91. https://doi.org/10.1007/s10965-020-02075-8

A. S. Pozdnyakov, N. P. Kuznetsova, S. A. Korzhova, T. G. Ermakova, T. V. Fadeeva, A. V. Vetohina, G. F. Prozorova, Russian Chemical Bulletin 64 (2015) 1440-1444. https://doi.org/10.1007/s11172-015-1029-9

S. H. Sargsyan, K. S. Margaryan, A. S. Sargsyan, Russian Journal of Applied Chemistry 91 (2018) 310-313. https://doi.org/10.1134/S1070427218020210

J. S. Kim, E. Kuk, K. N. Yu, J.-H. Kim, S. J. Park, H. J. Lee, S. H. Kim, Y. K. Park, Y. H. Park, C.-Y. Hwang, Y. -K. Kim, Y.-S. Lee, D.H. Jeong, M.-H. Cho. Nanomedicine: Nanotechnology, Biology and Medicine 3(1) (2007) 95-101. https://doi.org/10.1016/j.nano.2006.12.001

M. Rai, A. Yadav, A. Gade. Biotechnology Advances 27(1) (2009) 76-83. https://doi.org/-10.1016/j.biotechadv.2008.09.002

C. A. Mecha, V. L. Pillay, Journal of Membrane Science 458 (2014) 149-156. https://doi.org/¬10.1016/j.memsci.2014.02.001

E. F. Panarin, Russian Chemical Bulletin 66(10) (2017) 1812-1820. https://doi.org/10.1007/-s11172-017-1952-z

A. S. Pozdnyakov, A. A. Ivanova, A. I. Emelyanov, T. G. Ermakova, G. F. Prozorova, Russian Chemical Bulletin 66 (2017) 1099-1103. https://doi.org/10.1007/s11172-017-1860-2

V. V. Kopeikin, E. F. Panarin, Doklady Chemistry 380(4-6) (2001) 277-279. https://doi.org/10.1023/A:1012396522426

M. Davoodbasha, S.-C. Kim, S.-Y. Lee, J.-W. Kim, Archives of Biochemistry and Biophysics 605 (2016) 49-58. https://doi.org/10.1016/j.abb.2016.01.013

L. A. Tatarova, T. G. Yermakova, Al. Al. Berlin, Ye. F. Razvodovskii, V. A. Lopyrev, N. F. Kedrina, N. S. Yenikolopyan, Polymer Science U.S.S.R. 24(10) (1982) 2529-2536. https://doi.org/10.1016/0032-3950(82)90127-7

G. F. Prozorova, S. A. Korzhova, T. V. Kon’kova, A. S. Pozdnyakov, T. G. Ermakova, T. V. Fadeeva, S. A. Vereshchagina, B. A. Trofimov, Russian Chemical Bulletin 60 (2011) 671. https://doi.org/10.1007/s11172-011-0104-0

K. S. Margaryan, S. H. Sargsyan, A. S. Sargsyan, Russian Journal of Applied Chemistry 89 (2016) 1261-1264. https://doi.org/10.1134/S1070427216080073

H. Hirai, N. Toshima, Polymer-attached catalysis in Tailored Metal Catalysts, Iwasawa, Ed., D. Reidel Pub. Co., Dordrecht, Holand, 1985, pp. 87-140. https://doi.org/10.1007/978-94-009-5261-4_2

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, Russian Chemical Reviews 80(3) (2011) 257. http://dx.doi.org/10.1070/RC2011v080n03ABEH004079

V.I. Roldugin, Russian Chemical Reviews 69(10) (2000) 821. https://dx.doi.org/10.1070/RC-2000¬v069n10ABEH000605

M.-C. Daniel, D. Astruc, Chemical Reviews 104 (1) (2004) 293-346. https://doi.org/-10.1021/cr030698+

V. V. Volkov, T. A. Kravchenko, V. I. Roldughin, Russian Chemical Reviews 82(5) (2013) 465. https://doi.org/10.1070/RC2013v082n05ABEH004325

B. I. Kharisov, O. V. Kharissova, U. Ortiz-Méndez, Handbook of Less Common Nanostructures, CRC Press, Taylor and Francis Group, Boca Raton, 2012, p. 828.

P.C. Lee, D. Meisel, The Journal of Physical Chemistry 86(17) (1982) 3391-3395. https://doi.org/10.1021/j100214a025

P. Yang, W. Zhang, Y. Du, X.J. Wang, Journal of Molecular Catalysis A: Chemical 260(1-2) (2006) 4-10. https://doi.org/10.1016/j.molcata.2006.06.045

E. J. Kim, J. H. Yeum, H. D. Ghim, S. G. Lee, G. H. Lee, H. J. Lee, S. I. Han, J. H. Choi, Polymer (Korea) 35(2) (2011) 161-165. https://www.cheric.org/PDF/PK/PK35/PK35-2-0161.pdf

S. V. Vasilyeva, M. A. Vorotyntsev, I. Bezverkhyy, E. Lesniewska, O. Heintz, R. Chassagnon, The Journal of Physical Chemistry C 112(50) (2008) 19878-19885. https://doi.org/-10.1021/jp805423t

O. A. Petrii, Russian Chemical Reviews 85(2) (2015) 159. http://dx.doi.org/10.1070/RCR4438

Z.-Y. Zhou, N. Tian, J.-T. Li, I. Broadwell, Sh.-G. Sun Chemical Society Reviews 40 (2011) 4167-4185 https://doi.org/10.1039/C0CS00176G

G. F. Prozorova, A. S. Pozdnyakov, S. A. Korzhova, T. G. Ermakova, M. A. Novikov, E. A. Titov, L. M. Sosedova, Russian Chemical Bulletin 63 (2014) 2126-2129. https://doi.org/-10.1007/s11172-014-0709-1

N. L. Mazyar, V. Annenkov, V. A. Kruglova, S. M. Anan'ev, E. N. Danilovtseva, A. V. Rokhin, S. V. Zinchenko, Russian Chemical Bulletin, International Edition 49(12) (2000) 2013-2017. https://doi.org/10.1023/A:1009571908805

A. S. Pozdnyakov, A. I. Emel’yanov, T. G. Ermakova, G. F. Polymer Science B 56 (2014) 238-246. https://doi.org/10.1134/S1560090414020122

Ch. S. Barrett, T. B. Masalsky, The structure of metals, Metallurgy, Moscow, USSR, 1984, p. 681

Published
25-01-2022
Section
Electrochemical Science